Chemical composition and toxicity of effluents from unhairing baths: case study of the Batna Unit, Algeria
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Abstract

Introduction/Purpose: The leather industry in Algeria contributes significantly to the economy, but its unhairing process generates highly polluted wastewater. This study aimed to characterize the chemical composition of unhairing bath effluents and assess their environmental toxicity.

Methods: The study focused on wastewater samples from the Batna tannery unit, where sheep and goat skins were processed. Thirteen samples were collected manually over 35 days (April 5–May 10, 2022), and standard chemical analyses were conducted to evaluate parameters such as pH, conductivity, total suspended solids (TSS), sulfides, ammonia ions, and proteins.

Results: The results showed that the wastewater had a high pH (12.47 on average), high conductivity (13.38 mS/cm), and significant levels of pollutants: sulfides (1120–1650 mg/L), TSS (862–2220 mg/L), and chemical oxygen demand (10.422–43.747 mg/L). Additionally, the wastewater contained free amino acids and proteins, products of partially hydrolyzed skin proteins, increasing its toxicity.

Conclusions:The study highlighted the severe environmental risks of untreated unhairing wastewater, underscoring the need for effective treatment solutions to mitigate pollution. The findings provide important insights into the environmental challenges of the leather industry and stress the importance of sustainable wastewater management.

Keywords

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DOI: 10.5937/vojtehg73-58266

References

Benhadji, A., Taleb Ahmed, M., Djelal, H. & Maachi, R. 2018. Electrochemical treatment of spent tan bath solution for reuse. Journal of Water Reuse and Desalination, 8(1), pp.123-134.https://doi.org/10.2166/wrd.2016.123

Durai, G. & Rajasimman, M. 2011. Biological treatment of tannery wastewater-a review,4(1),pp.1-17.https://doi.org/10.3923/jest.2011.1.17

Floqi, T., Vezi, D. & Malollari, I. J. D. 2007. Identification and evaluation of water pollution from Albanian tanneries.Dessalination, 213(3), 56-64.https://doi.org/10.1016/j.desal.2006.03.603

Hasan, M. J., Alam, M. S., Mim, S., Haque, P. & Rahman, M. M. 2024. Pre-tanning of goatskin by minimizing chemical usage using crude protease enzyme for crust leather preparation.

Hashem, M. A., Khan, M. N. Z., Roy, P. & Hasan, M. A. 2021. Effect of Oxidizers on Sulphide Removal from Hair Dissolving Liming Wastewater in Tannery. Journal of Engineering Science, 12(3), 67-72. https://doi.org/10.3329/jes.v12i3.57480

Islam, B., Musa, A., Ibrahim, E., Sharafa, S. A., Elfaki, B. M. J. J. O. F. P. & Industries 2014. Evaluation and characterization of tannery wastewater. Journal Of Forest Products & Industries,3(3), 141-150.

Mendoza-Roca, J., Galiana-Aleixandre, M., Lora-García, J. & Bes-Piá, A. 2010. Purification of tannery effluents by ultrafiltration in view of permeate reuse. Separation and purification technology, 70(2010), 296-301.https://doi.org/10.1016/j.seppur.2009.10.010

Morera, J. M., Bartolí, E. & Gavilanes, R. M. 2016. Hide unhairing: achieving lower pollution loads, decreased wastewater toxicity and solid waste reduction. Journal of cleaner production, 112(4), 3040-3047.https://doi.org/10.1016/j.jclepro.2015.11.028

Rodier, J., Geoffray, C. & Rodi, L. 1996. L'analyse de l'eau: eaux naturelles, eaux residuaires, eau de mer: chimie, physico-chimie, bacteriologie, biologie, Dunod.

Sawadogo, R., Guiguemde, I., Diendere, F., Diarra, J., Bary, A. J. I. J. O. B. & Sciences, C. 2012. Caractérisation physico-chimique des eaux résiduaires de tannerie: cas de l’usine TAN ALIZ à Ouagadougou/Burkina Faso. International. Journal. Biological and chemical Sceince ,6(6), 7087-7095.http://dx.doi.org/10.4314/ijbcs.v6i6.43

Tamersit, S. & Bouhidel, K.-E. 2020. Treatment of tannery unhairing wastewater using carbon dioxide and zinc cations for greenhouse gas capture, pollution removal and water recycling. Journal of Water Process Engineering, 34, 101120.https://doi.org/10.1016/j.jwpe.2019.101120

Tamersit, S., Bouhidel, K.-E. & Zidani, Z. 2018. Investigation of electrodialysis anti-fouling configuration for desalting and treating tannery unhairing wastewater: Feasibility of by-products recovery and water recycling. Journal of environmental management, 207, 334-340. https://doi.org/10.1016/j.jenvman.2017.11.058

Zhao, J., Wu, Q., Tang, Y., Zhou, J. & Guo, H. 2022. Tannery wastewater treatment: conventional and promising processes, an updated 20-year review. Journal of Leather Science and Engineering, 4, 10. https://doi.org/10.1186/s42825-022-00082-7

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